Warm Toes in a Snow Shelter
1Every January, Scout Troop 214 spends two nights sleeping in snow shelters that the scouts dig into deep drifts. The air outside often drops to −12 °C at night, and the inside of a shelter usually stays a little below freezing. Last year, several scouts said that cold toes kept them awake. This year, troop leader Ms. Odalys Fuentes gave scouts Thandiwe Mokoena and Ilias Petrakis a design challenge: build a toe warmer that slips into a pocket at the foot of a sleeping bag and stays warm from bedtime until morning.
2Ms. Fuentes explained how many store-bought warmers work. Inside a cloth pouch, iron reacts with oxygen from the air and slowly forms rust, a new substance. Salt and water speed the reaction up, and a light, spongy mineral called vermiculite holds the water. Each pouch is kept in an airtight bag until it is needed. Following the scouts' plan, Ms. Fuentes, wearing gloves and goggles, filled each test pouch with 20 g of iron, 2 g of salt and 5 g of vermiculite and sewed it shut.
3The troop set two criteria for a pouch. First, it must read 35 °C or more at every reading from the 1-hour reading through the 8-hour reading, so it warms up soon after bedtime and lasts the night. Second, it must stay below 50 °C at every reading, because a pouch that is too hot can burn skin even through a sock.
4For Test 1, the scouts changed only the size of the iron grains: fine powder, coarse powder or small filings. Each pouch had 6 mL of water. Ms. Fuentes opened the bags at the same moment, and each pouch went inside a rolled-up fleece blanket in her garage, which stayed at 2 °C. A probe taped to each pouch recorded its temperature. As a control, a fine-powder pouch with 6 mL of water stayed closed in its airtight bag inside a fourth blanket. It read 2 °C for the whole test. After the test, the iron in the three open pouches had turned reddish-brown.